By D.E. Levy
In recent times C-glycoside chemistry has been one of many major themes in carbohydrate chemistry, not just as a result of artificial demanding situations posed, but additionally simply because C-glycosides have the capability to function carbohydrate analogues proof against metabolic methods. as a result, this type of compounds is presently receiving a lot curiosity as a possible resource of healing brokers for scientific use. This booklet offers a extensive assurance of a number of the man made tools to be had for the training of C-glycosides, and illustrates the attention-grabbing breadth of connections among carbohydrate chemistry and glossy common artificial natural chemistry by means of together with subject matters comparable to transition-metal catalysis, radical chemistry, cycloaddition and rearrangement techniques. furthermore, within the ultimate bankruptcy of the ebook, the syntheses of C-di and trisaccharides said via 1994 are reviewed. This good organised account of the unreal chemistry during this box will end up to be very priceless to quite a lot of researchers and complex scholars, either as an advent to the subject and for reference.
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Additional resources for The Chemistry of C-Glycosides (Tetrahedron Organic Chemistry)
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TolO ~ ~ 'cH~ To,d Benzoic Acid tert-Butyl Isocyanate S-~-Methylbenzylamine Chromatography Ph ~ OTol ~ NmCOPh OTol CONHtBu Told 1. Conc. FormicAcid 2. ,,, CONHtBu TolO 11" Conc. FormicAcid 2. 3 N---COPh TolO C-Glycosidic Heterocycles f r o m Nitriles O. , 21 demonstrated that a wide variety of heterocycles may be derived from these compounds. Particularly interesting is the variety of compatible protecting groups including benzoyl, p-nitrobenzoyl, and acetonides. 3 and the reader is referred to the original text for structural and experimental details.