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Additional resources for Reviews of Environmental Contamination and Toxicology Volume 217
This also leads to developing more complex molecules that have a greater likelihood for chiral centers. Chiral Pesticides: Identiﬁcation, Description… 19 ChirBase, the enantioselective separations database, contains entries for 25 of the 97 fungicides (26%). There are 465 records for these 25 pesticides (431 in LC, 6 in GC, and 28 in CE databases). Diniconazole has the most entries, with 72 total, and 69 of those are found in the LC database. The number of entries found for each fungicide in each ChirBase database is listed in Table 2.
Chiral features (constrained) 5 (4) 2 (2) 1 1 2 1 1 6 (4) 1 1 2 2 1 4 (Y) 1 11 (2) 1 1 1 1 1 1 1 1 Insecticide name Heptachlor Heptenophos Heterophos Hydroprene Imiprothrin Indoxacarb IPSP Isobenzan Isofenphos Isopropyl O-(methoxyaminothiophosphoryl)salicylate Juvenile hormone I Juvenile hormone II Juvenile hormone III Kelevan Kinoprene Lepimectin Leptophos Lufenuron Malathion Mecarphon Mephosfolan Mesulfenfos Methamidophos Methoprene Y Y (S)- Carbophos, maldison, mercaptothion (S)- Isocarbophos, isocarbofos S-Ethylsulﬁnylmethyl O,Odiisopropyl phosphorodithioate (S)- Meso?
4 as an example of an acid herbicide that can be paired with chiral esters or salts, but the herbicide itself is not chiral. Any achiral acid herbicide that is paired with such chiral moieties will be chiral as long as the bonding is sustained. , ester hydrolysis). For clarity, please see footnotes in the tables for such compounds. , 3,4-DP; 2-(3,4-dichlorophenoxy)propanoic acid], but these pesticides may contain additional chiral centers (and thus stereoisomers) that depend on the formulation.