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By A. C. Knipe, W. E. Watts

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Acta, 82, 769 (1998). , in Lipofuscin and Ceroid Pigments (Ed. Porta, E. ), Plenum Press, New York, 1990, pp. , and Sayre, L. , J. Org. , 64, 5732 (1999). , 40, 8849 (1999). Black, D. , Adv. , 3, 85 (1999); Chem. , 130, 223121 (1999). , J. Phys. Org. , 12, 708 (1999). (a) For a review of this approach, see: Brady, P. A. and Sanders, J. K. , Chem. Soc. , 26, 327 (1997); (b) Polyakov, V. , Nelen, M. , Ryabov, A. , and Eliseev, A. , J. Phys. Org. , 12, 357 (1999). (a) Johnson, J. , Todd, S. , Gardner, J.

The enol tautomers also undergo oxidative cyclization to give benzofurans, losing an isopropyl group in the process. 201 Thermodynamic parameters from temperature studies of the equilibrium give more information about the structures of the complexes; for example, the enol penetrates further into the cavity of the cyclodextrin, as conīŦrmed by 1 H NMR spectroscopy. Nitrosation of benzoylacetone is slowed in the presence of the cyclodextrin, consistent with a protective effect arising from the strong binding to the enol.

1, 157 (1999); Chem. , 131, 88157 (1999). Cogan, D. , Tetrahedron, 55, 8883 (1999). 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 1 Reactions of Aldehydes and Ketones and their Derivatives 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 43 Butkus, E. , Synlett, 1999, 234; Chem. , 130, 182199 (1999). Davis, F. A. and Andemicheal, Y.

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