Download Metal-metal bonding by J. F. Berry (auth.), Gerard Parkin (eds.) PDF

By J. F. Berry (auth.), Gerard Parkin (eds.)

John Berry: Metal-Metal Bonds in Chains of 3 or extra steel Atoms: From Homometallic to Heterometallic Chains.- Malcolm Chisholm: Electronically Coupled MM Quadruple Bonded Complexes of Molybdenum and Tungsten.- Philip energy: Transition steel Complexes Stabilized by means of cumbersome Terphenyl Ligands: purposes to Metal–Metal Bonded Compounds.- Gerard Parkin: Metal–Metal Bonding in Bridging Hydride and Alkyl Compounds.- Roland Fischer and Gernot Frenking: constitution and Bonding of steel wealthy Coordination Compounds Containing Low Valent Ga(I) and Zn(I) Ligands.- Mike Hill: Homocatenation of steel and Metalloid major team Elements.- Constandinos A. Tsipis: Aromaticity/Antiaromaticity in "Bare" and ‘‘Ligand-Stabilized’’ earrings of steel Atoms.- Alexander Boldyrev: All-Transition steel Aromaticity and Antiaromaticity.

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6 EPR Spectroscopy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 Optical Spectra . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 IVCT and Charge Resonance Bands. . . . . . . . . . . . . . . . . . . . . . . . . 2 Metal-to-Bridge Charge Transfer Bands . . . . . . . . . . . . . . . . . . .

H. A. Cotton. H. Chisholm 1 Introduction The first example of the linking of two MM quadruple bonds was discovered by McCarley who found that two Mo2 units could be linked together by bridging halides if there were attendant ligands that were labile as shown in (1) [1–3]. MeOH/2 !  Cl/2 2 C 4MeOH (1) The molecular structure of the tetramolecular molybdenum complex consisted of a planar rectangular Mo4 unit with short and long distances indicative of only weak MM bonding interactions between the two Mo4C 2 centers.

Syntheses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Molecular Structures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Electronic Coupling: Frontier Molecular Orbital Interactions and Electronic Structure Calculations . . . . . . . . . . .

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